Llullaillaco is a stratovolcano at the border of Argentina (Salta Province) and Chile. It lies in the Puna de Atacama, a region of very high volcanic peaks on a high plateau within the Atacama Desert, one of the driest places in the world. It is the second highest volcano in the world[citation needed], and it is also the seventh highest mountain of the Andes.

The peak's name comes from the Aymara for "murky water": llulla= dirty and yacu= water. Other sources propose it to have originated from Quechua Lullac= lie, Yacu= water: "lying (or treacherous) water".
It has been confirmed that Incas climbed Llullaillaco in the pre-Columbian period. Artifacts on the summit constitute the highest evidence of human presence worldwide before the late nineteenth century. Also, the huáqueros may have also reached its summit and those of other mountains in the region during their searches. The first recorded ascent was on December 1, 1952, by Bión González and Juan Harseim.
Geology
Two major geological stages can be highlighted in the history of the volcano: Llullaillaco I, the ancestral primary volcano, dates back to the Pleistocene. Two very eroded cones with associated lava flows, up to 20 km in length, distributed mainly to the West, evidence these stages.

There are reports of eruptions in 1854, 1868, and 1877, possibly causing the youngest lava flows in the area, which are easily recognizable because of their very dark appearance.
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